Question:
Balance the given Reaction:
Cu + HNO3⟶Cu(NO3)2+NO+H2O
Cu + HNO3⟶Cu(NO3)2+NO+H2O
Solution:
NO3-+4H++3e-⟶NO + 2H2O .......(2)
Equation (1) × 3 + Equation (2) × 2 (for equalizing electrons)
3Cu⟶3Cu2++6e-
2NO3-+ 8H + + 6e-⟶2NO+4H2O
But 8H+ + 8NO3- ⟶ 8HNO3
The 6NO32- combine with Cu2+
∴ Balanced equation is,
3Cu+8HNO3⟶3Cu(NO3)2+2NO+4H2O
Now,
Cu⟶Cu2++ 2e-.......(1)NO3-+4H++3e-⟶NO + 2H2O .......(2)
Equation (1) × 3 + Equation (2) × 2 (for equalizing electrons)
3Cu⟶3Cu2++6e-
2NO3-+ 8H + + 6e-⟶2NO+4H2O
_______________________________
3Cu+2NO3- + 8H+⟶3Cu2+ + 2NO + 4H2OBut 8H+ + 8NO3- ⟶ 8HNO3
The 6NO32- combine with Cu2+
∴ Balanced equation is,
3Cu+8HNO3⟶3Cu(NO3)2+2NO+4H2O